Coordination Compounds
The sum of coordination number and oxidation number of the metal M in the complex [M(en)2(C2O4)]Cl (where en is ethylenediamine) is
9
6
7
8
B.
6
Given complex compound is [M(en)2(C2O4)]Cl
Let oxidation number of M is x
therefore, x- 2 - 2 = -1
x = +3
Now, as coordination number is defined as the total number of binding sites attached to the metal.Hence, in the given complex coordination number is 6.
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Predict the number of unpaired electrons in the square planar [Pt(CN)4,]2– ion.
The hexaquo manganese(II) ion contains five unpaired electrons, while the hexacynoion contains only one unpaired electron. Explain using crystal field theory.
Identify the ligands from the following coordination compounds:
(a) [Co(en)2Cl(NO2)2]
(b) K[Co(CN)(CO2)(NO)]
(c) K3[Al(OH)6]
(d) [Co(H2O)2(NH3)4](OH)3
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