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Coordination Compounds

Question
CBSEENCH12007508
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Explain the following:
Violet coloured [Cr(H2O)6]3+ becomes bright blue when reduced to [Cr(H2O)6]2+

Solution
[Cr(H2O)6]3+ violet coloured changes to blue coloured [Cr(H2O)6]2+ when reduced because its Δ0 gets lowered and due to which in place of yellow region absorbed by [Cr(H2O)6]3+ now orange red region is absorbed and hence [Cr(H2O)]2+ become blue as blue is the complementary colour of orange.

Some More Questions From Coordination Compounds Chapter

Explain on the basis of valence bond theory that [Ni(CN)4]2–  ion with square planar is diamagnetic and the [NiCl4]2– ion with tetrahedral geometry is paramagnetic.

Predict the number of unpaired electrons in the square planar [Pt(CN)4,]2– ion.

The hexaquo manganese(II) ion contains five unpaired electrons, while the hexacynoion contains only one unpaired electron. Explain using crystal field theory.

Calculate the overall complex dissociation equilibrium constant for the Cu(NH3)42+ion, given β4 for this complex is 2.1 x 1013.

Identify the ligands from the following coordination compounds:
(a)    [Co(en)2Cl(NO2)2]
(b)    K[Co(CN)(CO2)(NO)]
(c)    K3[Al(OH)6]
(d)    [Co(H2O)2(NH3)4](OH)3

Write IUPAC name of the following complexes:
(a)    [Fe(H2O)6]SO4
(b)    [Cu(en)2(NO3)2

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