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Coordination Compounds

Question
CBSEENCH12007398
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What is the oxidation state of the metal in the following coordiantion compound?
(i) Ni in Ni(CO)4    (ii) Co in [Co(CO) 4]–

Solution

(i) The oxidation state of nickel is zero.

Ni =x
CO=0

therefore oxidation state is 0

(ii) The oxidation state of cobalt is –1.

Co=x
CO=0
anion=+1

x+0=1

Therefore oxidation state is 1.


Some More Questions From Coordination Compounds Chapter

Explain on the basis of valence bond theory that [Ni(CN)4]2–  ion with square planar is diamagnetic and the [NiCl4]2– ion with tetrahedral geometry is paramagnetic.

Predict the number of unpaired electrons in the square planar [Pt(CN)4,]2– ion.

The hexaquo manganese(II) ion contains five unpaired electrons, while the hexacynoion contains only one unpaired electron. Explain using crystal field theory.

Calculate the overall complex dissociation equilibrium constant for the Cu(NH3)42+ion, given β4 for this complex is 2.1 x 1013.

Identify the ligands from the following coordination compounds:
(a)    [Co(en)2Cl(NO2)2]
(b)    K[Co(CN)(CO2)(NO)]
(c)    K3[Al(OH)6]
(d)    [Co(H2O)2(NH3)4](OH)3

Write IUPAC name of the following complexes:
(a)    [Fe(H2O)6]SO4
(b)    [Cu(en)2(NO3)2

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