The p-Block Elements
The variation of the boiling point of the hydrogen halides in the order HF > HI > HBr > HCl. What explains the higher boiling point of hydrogen fluoride?
The electronegativity of fluorine is much higher than for other elements in the group
There is strong hydrogen bonding between HF molecules
The bond energy of HF molecules is greater than in other hydrogens halides
The effect of nuclear shielding is much reduced in fluorine which polarises the HF molecules
B.
There is strong hydrogen bonding between HF molecules
There is a strong hydrogen bonding between HF molecules. Hence, the boiling point is highest for HF.
HF > HI > HBr > HI
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