The p-Block Elements

Question

Assign a reason for the following statement:
Phosphorus (P4) is more reactive than nitrogen (N2).

Answer

Nitrogen molecule is a diatomic and the two nitrogen atoms are linked by a triple bond (N≡ N) forming (pi-pi) bond. As the bond dissociation energy is very high (946 kj mol–1), it is not possible to cleave the triple bond so easily. Therefore, phosphorus (P4) is more reactive than nitrogen (N2).

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