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Electrochemistry
Question
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Iron does not rust even if the zinc coating is broken in a galvanised iron pipe but, rusting occurs much faster if the tin coating over iron is broken. Explain?

Answer

Zinc is more electro-positive than iron. Therefore, as long as zinc is there on the iron pipe, zinc acts as anode and the iron as cathode. As a result, rusting of iron is prevented.
On the other hand, tin is less electro-positive than iron. Therefore, when tin coating over iron gets broken, iron acts as anode and gets oxidised. Thus even when tin is there, the exposed iron gets rusted.

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