Haloalkanes and Haloarenes
Haloalkanes undergo nucleophillic substitution reaction due to high electronegativity of the halogen atom, the C—X bond in haloalkanes (alkyl halides) is slightly polar, thereby the C-atom acquires a slight positive charge (≡ C+δ—X–δ). Hence, C-atom is a good target for attack by nucleophiles (electron easily rich species). Therefore, the X-atom of the halo-alkane is replaced by a nucleophile easily.
Nu : + R+δ—Xδ → R—Nu + X–
On the other hand, in haloarenes the halogen atom releases electron to the benzene nucleus relatively electron-rich with respect to halogen atom. As a result, the electrophile attacks at ortho and para position. Hence, haloarenes undergo electrophilic substitution reactions.
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Draw the structures of major monohalo products in each of the following reactions:
Draw the structures of major monohalo products in each of the following reactions:
Draw the structures of major monohalo products in each of the following reactions:
Draw the structures of major monohalo products in each of the following reactions:
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