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Haloalkanes And Haloarenes

Question
CBSEENCH12007599

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Solution

To have three isomeric monochlorides, the isomer of the alkane of the molecular formula C5H12 should contain three different types of H-atoms

The equivalent hydrogens are grouped as a, b and c. The replacement of equivalent hydrogens will give the same product.
CaH3 CbH2 CcH2 CbH2 CaH3 

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