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Haloalkanes And Haloarenes

Question
CBSEENCH12007609
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Arrange each set of compounds in order of increasing boiling points:

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Solution
Short Answer

1-bromobutane is a primary alkyl halide whereas 2-bromobutane is secondary alkyl halide. The nucleophile approaching is more hindered in 2- bromobutane than in 1-bromobutane. Therefore, 1- bromobutane reacts more rapidly than 2- bromobutane by an SN2 mechainsm. 
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Some More Questions From Haloalkanes and Haloarenes Chapter

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

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Draw the structures of major monohalo products in each of the following reactions:


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Draw the structures of major monohalo products in each of the following reactions:


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Draw the structures of major monohalo products in each of the following reactions:
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Draw the structures of major monohalo products in each of the following reactions:

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Arrange each set of compounds in order of increasing boiling points:
Bromomethane, Bromoform, Chloro-methane, Dibromomethane.

Arrange each set of compounds in order of increasing boiling points:
1-chloropropane, Isopropyl chloride, 1-chlorobutane.

Arrange each set of compounds in order of increasing boiling points:

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