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Haloalkanes and Haloarenes
Question
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Arrange the following compounds according to their relative reactivity with the reagents mentioned against them.

(a)    C6H5CH2CH2Br, C6H5CHBrCH3 and C6H5CH = CHBr with alcoholic silver nitrate.

(b)    C6H5CH2Br, n-C6H13 Br and C6H5Br with ale. AgNO3 or with KCN.

(c)    t-Butyl chloride, sec-butyl chloride and CCl4 with ale. silver nitrate.

(d)    m-Nitro chlorobenzene, 2, 4-dinitro-chlorobenzene and p-nitro chlorobenzene with sodium ethoxide.

Answer

(a) It is an SN1 reaction.

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