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General Principles And Processes Of Isolation Of Elements

Question
CBSEENCH12011493

In cyanide extraction process of silver from argentite ore, the oxidising and reducing agents are respectively.

  • O2 and CO2

  • O2 and Zn dust

  • HNO3 and Zn dust

  • HNO3 and CO

Solution

B.

O2 and Zn dust

The extraction of silver involves in cyanide process are:

(i) Ag2S + 2CN- + O2    2[Ag(CN)2]- + SO2(ii) [Ag(CN)2]- + Zn     [Zn(CN)4]2- + Ag

Thus, in equation (i) O2 act as oxidising agent (Oxidise sulphide to SO2) and in (ii) Zn act as reducing agent (reduce Ag+ to Ag).