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Aldehydes, Ketones And Carboxylic Acids

Question
CBSEENCH12011239

Match the compounds given in the list I with List II and select the suitable option using the code given below.

 

List I

 

List II

A.

Benzaldehyde

1.

Phenolphtalein

B.

Phthalic anhydride

2.

Benzoin Condensation

C.

Phenyl benzoate

3.

Oil of wintergreen

D.

Methyl salicylate

4.

Fries rearrangement

  • A
    B
    C
    D
    4
    1
    3
    2
  • A
    B C D
    4 2 3 1
  • A
    B C D
    2 3 4 1
  • A
    B C D
    2 1 4 3

Solution

D.

A
B C D
2 1 4 3

A. Benzoin condensation: When an ethanolic solution of benzaldehyde is heated with a strong alkali like KCN or NaCN, we get benzoin.
B. Formation of Phenolphthalein: When phenol is treated with a pthalic anhydride in the presence of concentrated H2SO4, it gives phenolphthalein, an indicator.
C. Fries rearrangement: When phenyl benzoate heated with anhydrous AlCl3 in the presence of inert solvent gives ortho and para - hydroxy benzophenone. In this rearrangement, there is a benzoyl group migration from the phenolic oxygen to an ortho and para - position.
D. Methyl salicylate: A chief constituent of oil of wintergreen