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The P-Block Elements

Question
CBSEENCH12011224

The variation of the boiling point of the hydrogen halides in the order HF >  HI > HBr > HCl. What explains the higher boiling point of hydrogen fluoride?

  • The electronegativity of fluorine is much higher than for other elements in the group

  • There is strong hydrogen bonding between HF molecules

  • The bond energy of HF molecules is greater than in other hydrogens halides

  • The effect of nuclear shielding is much reduced in fluorine which polarises the HF molecules

Solution

B.

There is strong hydrogen bonding between HF molecules

There is a strong hydrogen bonding between HF molecules. Hence, the boiling point is highest for HF.
HF > HI > HBr > HI