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Aldehydes, Ketones And Carboxylic Acids

Question
CBSEENCH12011125

The reaction by which benzaldehyde cannot be prepared? 

  •  +CrO2Cl2 and CS2 followed by H3O+
  •  +H2 in presence of anhydrous AlCl3.
  •  +CO +HCl in presence of anhydrous AlCl3
  •  +Zn/Hg and Conc. HCl

Solution

D.

 +Zn/Hg and Conc. HCl
Thus, from the reagents given in option (d) benzaldehyde is not obtained