The freezing point of benzene decreases by 0.45°C when 0.2 g of acetic acid is added to 20 g of benzene. If acetic acid associates to form a dimer in benzene, percentage association of acetic acid in benzene will be
(K_f for benzene = 5.12 K kg mol^–1)

64.6%

80.4%

74.6%

94.6%

Solution

94.6%

In benzene
2CH₃COOH ⇌ (CH₃COOH)₂
$straight i space equals space 1 space plus space open parentheses 1 half minus 1 close parentheses straight i space minus space 1 minus straight alpha over 2 Here space straight alpha space is space degree space of space association increment straight T subscript straight f space equals space iK subscript straight f straight m 0.45 space equals space open parentheses 1 minus straight alpha over 2 close parentheses left parenthesis 5.12 right parenthesis fraction numerator open parentheses begin display style fraction numerator 0.2 over denominator 60 end fraction end style close parentheses over denominator begin display style 20 over 1000 end style end fraction 1 minus straight alpha over 2 space equals space 0.527 straight alpha space equals space 0.945 percent sign space degree space of space association space equals space 94.5 percent sign$

Some More Questions From Solutions Chapter

Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL at 37⁰C.

Suppose a solid solution is formed between two substances, one whose particles are very large and the other whose particles are very small. What kind of solid solution is this likely to be?

Amongst the following compunds identify which are insoluble, partially soluble and highly soluble in water?
(i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform, (vi) pentanol.

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Solutions

The freezing point of benzene decreases by 0.45°C when 0.2 g of acetic acid is added to 20 g of benzene. If acetic acid associates to form a dimer in benzene, percentage association of acetic acid in benzene will be
(K_f for benzene = 5.12 K kg mol^–1)

64.6%

80.4%

74.6%

94.6%

Some More Questions From Solutions Chapter

Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL at 37⁰C.

Suppose a solid solution is formed between two substances, one whose particles are very large and the other whose particles are very small. What kind of solid solution is this likely to be?

Amongst the following compunds identify which are insoluble, partially soluble and highly soluble in water?
(i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform, (vi) pentanol.

Two liquids A and B boils at 145⁰C and 190⁰C respectively. Which of them has a higher vapour pressure at 80⁰C ?

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Solutions

The freezing point of benzene decreases by 0.45°C when 0.2 g of acetic acid is added to 20 g of benzene. If acetic acid associates to form a dimer in benzene, percentage association of acetic acid in benzene will be(Kf for benzene = 5.12 K kg mol–1) 64.6% 80.4% 74.6% 94.6%

Some More Questions From Solutions Chapter

Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL at 370C.

Suppose a solid solution is formed between two substances, one whose particles are very large and the other whose particles are very small. What kind of solid solution is this likely to be?

Amongst the following compunds identify which are insoluble, partially soluble and highly soluble in water?(i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform, (vi) pentanol.

Two liquids A and B boils at 1450C and 1900C respectively. Which of them has a higher vapour pressure at 800C ?

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

The freezing point of benzene decreases by 0.45°C when 0.2 g of acetic acid is added to 20 g of benzene. If acetic acid associates to form a dimer in benzene, percentage association of acetic acid in benzene will be
(K_f for benzene = 5.12 K kg mol^–1)

64.6%

80.4%

74.6%

94.6%

Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL at 37⁰C.

Amongst the following compunds identify which are insoluble, partially soluble and highly soluble in water?
(i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform, (vi) pentanol.

Two liquids A and B boils at 145⁰C and 190⁰C respectively. Which of them has a higher vapour pressure at 80⁰C ?