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General Principles And Processes Of Isolation Of Elements

Question
CBSEENCH12010692

Which method of purification is represented by the following equation

Ti left parenthesis straight s right parenthesis space plus 2 straight I subscript 2 space left parenthesis straight g right parenthesis space rightwards arrow with 523 space straight K on top space Til subscript 4 space left parenthesis straight g right parenthesis
rightwards arrow with 1700 space straight K on top space Ti space left parenthesis straight s right parenthesis space plus space 2 space straight I subscript 2 space left parenthesis straight g right parenthesis

  • zone refining

  • cupellation

  • Polling

  • Van-Arkel

Solution

D.

Van-Arkel

Van-Arkel (and de-Boiser) process is based on the thermal decomposition of a volatile compound like an iodide, which is first formed by direct combination of metal to be purified and iodine.
The metallic iodide is then decomposed when heated at a higher temperature and thus the metal obtained in the purest form. Titanium and zirconium are purified by this method.