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Aldehydes, Ketones And Carboxylic Acids

Question
CBSEENCH12010298

Write the equations involved in the following reactions:

(i) Reimer - Tiemann reaction

(ii) Williamson’s ether synthesis

Solution

(i) Reimer-Tiemann reaction:

 

(ii) Williamson’s ether synthesis:

When alkyl halide is reacted with sodium alkoxide it gives ether

R-X          +   R’ – ONa           ----->  R – O - R’ + NaX

Alkyl halide    sodium alkoxide            ether


An example is a reaction of sodium ethoxide with chloroethane to form diethyl ether and sodium chloride.

Na+C2H5O- + C2H5Cl ---> C2H5OC2H5 + Na+Cl-