-->

General Principles And Processes Of Isolation Of Elements

Question
CBSEENCH12009902

State the role of silica in the metallurgy of copper.

Solution
During the roasting of pyrite ore, a mixture of FeO and Cu2O is obtained.
2CuFeS2 +O2  Cu2S +2FeS +SO22Cu2S +3O2  2Cu2O +2SO22Fe +3O2  FeO +2SO2 

The role of silica in the metallurgy of copper is to remove the iron oxide obtained during the process of roasting as ‘slag’. FeS obtained from roasting iron sulphide ore is converted into FeO which forms iron silicate with silica (SiO
2). Thus FeO is removed as FeSiO(slag).

FeO(s) + SiO2  FeSiO3(s)