Question

Why carboxylic acids have a higher boiling point than alcohols of same number of carbon atoms?

Solution

Carboxylic acids have higher boiling point than alcohols due to more extensive association of carboxylic acid molecules through intermolecular hydrogen bonding. The hydrogen bonds are not broken completely even in the vapour phase. Hence carboxylic acids have higher boiling points than alcohols.

Some More Questions From Aldehydes, Ketones and Carboxylic Acids Chapter

Write the structures of the following compounds.
Di-sec-butyl ketone

Write the structures of the following compounds.
4-fluoro acetophenone.

Write the structures of the following reactions:

Write the structures of products of the following reactions:

Arrange the following compounds in increasing order of their boiling points:
CH₃CHO, CH₃CH₂OH, CH₃OCH₃, CH₃CH₂CH₃.

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions:
Ethanal, Propanal, Propanone, Butanone.

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions:
Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.

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Aldehydes, Ketones And Carboxylic Acids

Why carboxylic acids have a higher boiling point than alcohols of same number of carbon atoms?

Some More Questions From Aldehydes, Ketones and Carboxylic Acids Chapter

Write the structures of the following compounds.
Di-sec-butyl ketone

Write the structures of the following compounds.
4-fluoro acetophenone.

Write the structures of the following reactions:

Write the structures of products of the following reactions:

Arrange the following compounds in increasing order of their boiling points:
CH₃CHO, CH₃CH₂OH, CH₃OCH₃, CH₃CH₂CH₃.

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions:
Ethanal, Propanal, Propanone, Butanone.

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions:
Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.

Predict the products of the following reactions:

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

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Aldehydes, Ketones And Carboxylic Acids

Why carboxylic acids have a higher boiling point than alcohols of same number of carbon atoms?

Some More Questions From Aldehydes, Ketones and Carboxylic Acids Chapter

Write the structures of the following compounds.Di-sec-butyl ketone

Write the structures of the following compounds.4-fluoro acetophenone.

Write the structures of the following reactions:

Write the structures of products of the following reactions:

Arrange the following compounds in increasing order of their boiling points:CH3CHO, CH3CH2OH, CH3OCH3, CH3CH2CH3.

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions: Ethanal, Propanal, Propanone, Butanone.

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions: Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.

Predict the products of the following reactions:

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

Write the structures of the following compounds.
Di-sec-butyl ketone

Write the structures of the following compounds.
4-fluoro acetophenone.

Arrange the following compounds in increasing order of their boiling points:
CH₃CHO, CH₃CH₂OH, CH₃OCH₃, CH₃CH₂CH₃.

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions:
Ethanal, Propanal, Propanone, Butanone.

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions:
Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone.