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The P-Block Elements

Question
CBSEENCH12006803

Why is dioxygen a gas but sulphur a solid?

Solution
Oxygen is smaller in size and thus  due to its small size complete its octet by forming  pπ = pπ bond. Therefore, O2 is a discrte molecule and the intermolecular forces of attraction are weak vander waals forces. Hence, O2 is a gas. While sulphur is large in size, cannot form pπ = pπ bonds. Therefore, in order to gain stability, it exists as S8 which is a solid.