-->

The P-Block Elements

Question
CBSEENCH12006802

Justify the placement of O, S, Se, Te and Po in the same group of the periodic table in terms of electronic configuraton, oxidation state and hydride formation. 

Solution

(i) Electronic configuration: They all have six electrons in the outermost shell and have ns2 np4 general electronic configuration.
(ii) Oxidation state: The outer configuration of all these elements is ns2 np4. Therefore, they complete their octet either by gaining two electrons or by sharing two electrons. Two types of oxidation states are shown by these elements.
(a) Negative oxidation state: Except the compound OF2 oxygen shows-2 oxidation state in all its compounds. Due to hgh electronegativity, it forms O2' ion in most of the metal oxides.
The electronegativities of S, Se, Te are low hence their compounds even with most electropositive elements are not more than 50% ionic. Hence S2–', Se2–' and Te2–' are less probable. Being a metal Po does not form Po2+ ion at all.
(b) Positive oxidation state: Oxygen does not show positive oxidation state except OF2(O = + 2). With the increase in atomic number of electro negativity is decreasd in this group, hence the tendency to show the positive oxidation states will increase. S, Se, Te, Po show + 4, +6 oxidation state in addition to + 2.
(iii) Hydride formation: All the elements O, S, Se, Te and Po form M2M type hydrides (where M = O, S, Se, Te and Po)