Calculate the cell emf at 25° C for the following cell:
Ni(s) | Ni²⁺ (0.01 M) || Cu²⁺ (0.1 M) | Cu(s)
[Given E°_Ni²⁺/Ni = – 0 25 V, ^E° Cu = + 0.34 V, 1 F = 96500]
Calculate the maximum work that can be accomplished by operation of this cell.

Solution

Ni(s) | Ni²⁺ (0.01 M) || Cu²⁺ (0.1 M) | Cu(s)
At anode Ni(s) → Ni²⁺ (aq) + 2e
At cathode Cu²⁺ + 2e → Cu(s)
Net cell reaction
$Nis) + {Cu}^{2 +} (aq) \to {Ni}^{2 +} (aq) + Cu (s) E_{cell} = E_{cell}^{0} - \frac{0.0591}{2} \log \frac{[{Ni}^{2 +}]}{[{Cu}^{2 +}]} E_{cell}^{0} = E_{\frac{{Cu}^{2 +}}{Cu}}^{0} - E_{\frac{{Ni}^{2 +}}{Ni}}^{0} + 0.34 V - (- 0.25 V) = 0.59 V thus 0.59 V - \frac{0.0591}{2} \log \frac{0.01}{0.1} 0.59 V - \frac{0.0591}{2} \log \frac{1}{10} 0.59 V - \frac{0.0591}{2} \times - (1) = 0.591 V + 0.295 = 0.6195 V ∆ G = - nE ° F - 2 \times 0.6195 V \times 96500 = - 11956.500 J ∆ G = - 119.5635 KJ ∆ G = W_{MAX} = 119.5635 KJ$

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Electrochemistry

Calculate the cell emf at 25° C for the following cell:
Ni(s) | Ni²⁺ (0.01 M) || Cu²⁺ (0.1 M) | Cu(s)
[Given E°_Ni²⁺/Ni = – 0 25 V, ^E° Cu = + 0.34 V, 1 F = 96500]
Calculate the maximum work that can be accomplished by operation of this cell.

Some More Questions From Electrochemistry Chapter

Suggest a way to determine the Λ°_m value of water.

The molar conductivity of 0.025 mol L^–1methanoic acid is 46.1 S cm² mol^–1. Calculate its degree of dissociation and dissociation constant. Give λ°(H⁺) = 349.6 S cm²mol^–1 and λ° (HCOO^– ) = 54.6 s cm² mol^–1.

If the current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons flow through the wire?

Suggest a list of metals that are extracted electrolytically.

Consider the reaction: Cr₂O₇^2– + 14H⁺ + 6e- → 2Cr³⁺ + 8H₂O
What is the quantity of electricity in coulombs needed to reduce 1 mol of Cr₂O₇^2-?

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Electrochemistry

Calculate the cell emf at 25° C for the following cell:Ni(s) | Ni2+ (0.01 M) || Cu2+ (0.1 M) | Cu(s)[Given E°Ni2+/Ni = – 0 25 V, E° Cu = + 0.34 V, 1 F = 96500]Calculate the maximum work that can be accomplished by operation of this cell.

Some More Questions From Electrochemistry Chapter

Suggest a way to determine the Λ°m value of water.

The molar conductivity of 0.025 mol L–1 methanoic acid is 46.1 S cm2 mol–1. Calculate its degree of dissociation and dissociation constant. Give λ°(H+) = 349.6 S cm2 mol–1 and λ° (HCOO– ) = 54.6 s cm2 mol–1.

If the current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons flow through the wire?

Suggest a list of metals that are extracted electrolytically.

Consider the reaction: Cr2O72– + 14H+ + 6e- → 2Cr3+ + 8H2OWhat is the quantity of electricity in coulombs needed to reduce 1 mol of Cr2O72-?

Write the chemistry of recharging the lead storage battery, highlighting all the materials that are involved during recharging.

Suggest two materials other than hydrogen that can be used as fuels in fuel cells.

Name the electrolyte used in fuel cell?

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

Calculate the cell emf at 25° C for the following cell:
Ni(s) | Ni²⁺ (0.01 M) || Cu²⁺ (0.1 M) | Cu(s)
[Given E°_Ni²⁺/Ni = – 0 25 V, ^E° Cu = + 0.34 V, 1 F = 96500]
Calculate the maximum work that can be accomplished by operation of this cell.

Suggest a way to determine the Λ°_m value of water.

The molar conductivity of 0.025 mol L^–1methanoic acid is 46.1 S cm² mol^–1. Calculate its degree of dissociation and dissociation constant. Give λ°(H⁺) = 349.6 S cm²mol^–1 and λ° (HCOO^– ) = 54.6 s cm² mol^–1.

Consider the reaction: Cr₂O₇^2– + 14H⁺ + 6e- → 2Cr³⁺ + 8H₂O
What is the quantity of electricity in coulombs needed to reduce 1 mol of Cr₂O₇^2-?