Explain why the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride?

Solution

The dipole moment of chlorobenzene is less than cyclohexyl chloride as in chloro benzene because C-Cl bond is sp² hybridised where as in cyclohexyl chloride the C-Cl bond is SP³ Hybridised . Since sp² has more s character and more electronegative than sp³. Also, In chlorobenzene resonance gives rise to partial double bond charcter to the carbon- halogen bond, making it stronger by reducing the polarity of the carbon -halogen bond. Hence, chlorobenzene is less polar than cyclohexyl chloride.

Some More Questions From Haloalkanes and Haloarenes Chapter

Write structures of the following compounds:
1-chloro-4-ethylcyclohexane

Write structures of the following compounds:
4-tert-Butyl-3-iodohaptane

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Haloalkanes And Haloarenes

Explain why the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride?

Some More Questions From Haloalkanes and Haloarenes Chapter

Write structures of the following compounds:
1-chloro-4-ethylcyclohexane

Write structures of the following compounds:
4-tert-Butyl-3-iodohaptane

Write structures of the following compounds:
1, 4-Dibromo but-2-ene

Write structures of the following compounds:
1-Bromo-4-sec butyl-2-methyl benzene.

Why is sulphuric acid not used during the reaction of alcohols with KI?

Write structures of different dihalogen derivatives of propane.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i) A single monochloride.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

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Haloalkanes And Haloarenes

Explain why the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride?

Some More Questions From Haloalkanes and Haloarenes Chapter

Write structures of the following compounds:1-chloro-4-ethylcyclohexane

Write structures of the following compounds:4-tert-Butyl-3-iodohaptane

Write structures of the following compounds:1, 4-Dibromo but-2-ene

Write structures of the following compounds:1-Bromo-4-sec butyl-2-methyl benzene.

Why is sulphuric acid not used during the reaction of alcohols with KI?

Write structures of different dihalogen derivatives of propane.

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:i) A single monochloride.

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

Write structures of the following compounds:
1-chloro-4-ethylcyclohexane

Write structures of the following compounds:
4-tert-Butyl-3-iodohaptane

Write structures of the following compounds:
1, 4-Dibromo but-2-ene

Write structures of the following compounds:
1-Bromo-4-sec butyl-2-methyl benzene.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i) A single monochloride.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.