Explain the reason:

The reactivity order of alkyl bromides is tert alkyl bromide > sec alkyl bromide > primary alkyl bromide.

Solution

i) The given order is follow the S_N1 mechanism. In which carbon halogen bond is break and form carbocation and halogen ion.
ii) The carbocation is formed is then attacked by nucleophile in step to complete the substitution reaction.
According to S_N1 mechanism more is stability of carbocation easy is formation of compound. Hence the order of alkyl bromides are given as;
3⁰ > 2⁰ > 1⁰
Since tertiary cation is more stable than secondary and secondary is more stable than primary.

Some More Questions From Haloalkanes and Haloarenes Chapter

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Haloalkanes And Haloarenes

Explain the reason:

The reactivity order of alkyl bromides is tert alkyl bromide > sec alkyl bromide > primary alkyl bromide.

Some More Questions From Haloalkanes and Haloarenes Chapter

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Arrange each set of compounds in order of increasing boiling points:
Bromomethane, Bromoform, Chloro-methane, Dibromomethane.

Arrange each set of compounds in order of increasing boiling points:
1-chloropropane, Isopropyl chloride, 1-chlorobutane.

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Haloalkanes And Haloarenes

Explain the reason:The reactivity order of alkyl bromides is tert alkyl bromide > sec alkyl bromide > primary alkyl bromide.

Some More Questions From Haloalkanes and Haloarenes Chapter

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Arrange each set of compounds in order of increasing boiling points:Bromomethane, Bromoform, Chloro-methane, Dibromomethane.

Arrange each set of compounds in order of increasing boiling points:1-chloropropane, Isopropyl chloride, 1-chlorobutane.

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

Explain the reason:

The reactivity order of alkyl bromides is tert alkyl bromide > sec alkyl bromide > primary alkyl bromide.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.

Arrange each set of compounds in order of increasing boiling points:
Bromomethane, Bromoform, Chloro-methane, Dibromomethane.

Arrange each set of compounds in order of increasing boiling points:
1-chloropropane, Isopropyl chloride, 1-chlorobutane.