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Haloalkanes And Haloarenes

Question

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Write a convenient method of preparation of iodoalkanes.

Solution

lodoalkane is conveniently prepared by the interaction of sodium iodide in acetone with a corresponding chloroalkane
.

stack bold R bold space bold minus bold space bold CH subscript bold 2 with bold Chloroalkane below bold space bold minus bold space bold Cl bold space bold plus bold space bold Nal bold space bold rightwards arrow with bold space bold space bold space bold Acetone bold space bold space bold space on top bold space bold space stack bold R bold space bold minus bold space bold CH subscript bold 2 with bold Iodoalkane below bold space bold minus bold space bold I bold space bold plus bold space bold NaCl

Some More Questions From Haloalkanes and Haloarenes Chapter

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Arrange each set of compounds in order of increasing boiling points:
Bromomethane, Bromoform, Chloro-methane, Dibromomethane.

Arrange each set of compounds in order of increasing boiling points:
1-chloropropane, Isopropyl chloride, 1-chlorobutane.

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