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Haloalkanes And Haloarenes

Question

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Unlike the chlorine atom in CH₃CI, that in chlorobenzene, C₆H₅Cl, is not easily replaced by the —OH group. Give reason.

Solution

Chlorine atom is easily replaced in alkyl chloride than chlorobenzene because chlorobenzene is greatly stabilized by resonance.

Some More Questions From Haloalkanes and Haloarenes Chapter

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Arrange each set of compounds in order of increasing boiling points:
Bromomethane, Bromoform, Chloro-methane, Dibromomethane.

Arrange each set of compounds in order of increasing boiling points:
1-chloropropane, Isopropyl chloride, 1-chlorobutane.

Arrange each set of compounds in order of increasing boiling points:

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