p-Dichlorobenzenes have higher melting points and lower solubilities than that of their o- and m-isomers. Why?

Solution

p- Dichlorobenzene have higher melting points and lower solubilities than that of their o- and m- isomers because the p-isomers is more symmetrical and therefore fits into a crystal lattice as a result the intermolecular forces.

Some More Questions From Haloalkanes and Haloarenes Chapter

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Haloalkanes And Haloarenes

p-Dichlorobenzenes have higher melting points and lower solubilities than that of their o- and m-isomers. Why?

Some More Questions From Haloalkanes and Haloarenes Chapter

Why is sulphuric acid not used during the reaction of alcohols with KI?

Write structures of different dihalogen derivatives of propane.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i) A single monochloride.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

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Haloalkanes And Haloarenes

p-Dichlorobenzenes have higher melting points and lower solubilities than that of their o- and m-isomers. Why?

Some More Questions From Haloalkanes and Haloarenes Chapter

Why is sulphuric acid not used during the reaction of alcohols with KI?

Write structures of different dihalogen derivatives of propane.

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:i) A single monochloride.

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i) A single monochloride.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.