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Haloalkanes And Haloarenes

Question

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Arrange the following to the increasing order of boiling point
(i)

(ii) CH₃CHCH₂CH₃

(iii) CH₃CH₂CH₂CH₂Br

(iv) (CH₃)₃ C—Cl

Solution

The boiling point haloalkanes decrease with increase in branching. Therefore the increasing order of boiling point is,
(iv) < (i) < (ii) < (iii).

Some More Questions From Haloalkanes and Haloarenes Chapter

Why is sulphuric acid not used during the reaction of alcohols with KI?

Write structures of different dihalogen derivatives of propane.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i) A single monochloride.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

Draw the structures of major monohalo products in each of the following reactions:

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