Iodoform gives precipitate with silver nitrate on heating while chloroform does not. why?

Solution

When chloroform reacts with AgNO₃ it form AgCl.

AgNO3 + CHCl3(chloroform) ---> AgCl + CHCl₂ + NO₃^-1
AgCl is a very soluble ppt in acq. sol. so, it tends to reionize more than staying precipitated.as its solubility is very high and especially with heating because its solubility product is high.
while in case of iodoform, it reacts with AgNO₃ to form AgI
AgNO₃ + CHI₃(Iodoform) -------------> AgI (ppt) + CHCl₂+ NO₃^-
AgI is less soluble in solution on heating as its solubility product is low.

Some More Questions From Haloalkanes and Haloarenes Chapter

Write structures of the following compounds:
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Haloalkanes And Haloarenes

Iodoform gives precipitate with silver nitrate on heating while chloroform does not. why?

Some More Questions From Haloalkanes and Haloarenes Chapter

Write structures of the following compounds:
1-chloro-4-ethylcyclohexane

Write structures of the following compounds:
4-tert-Butyl-3-iodohaptane

Write structures of the following compounds:
1, 4-Dibromo but-2-ene

Write structures of the following compounds:
1-Bromo-4-sec butyl-2-methyl benzene.

Why is sulphuric acid not used during the reaction of alcohols with KI?

Write structures of different dihalogen derivatives of propane.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i) A single monochloride.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

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Haloalkanes And Haloarenes

Iodoform gives precipitate with silver nitrate on heating while chloroform does not. why?

Some More Questions From Haloalkanes and Haloarenes Chapter

Write structures of the following compounds:1-chloro-4-ethylcyclohexane

Write structures of the following compounds:4-tert-Butyl-3-iodohaptane

Write structures of the following compounds:1, 4-Dibromo but-2-ene

Write structures of the following compounds:1-Bromo-4-sec butyl-2-methyl benzene.

Why is sulphuric acid not used during the reaction of alcohols with KI?

Write structures of different dihalogen derivatives of propane.

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:i) A single monochloride.

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields:Four isomeric monochlorides.

Draw the structures of major monohalo products in each of the following reactions:

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

Write structures of the following compounds:
1-chloro-4-ethylcyclohexane

Write structures of the following compounds:
4-tert-Butyl-3-iodohaptane

Write structures of the following compounds:
1, 4-Dibromo but-2-ene

Write structures of the following compounds:
1-Bromo-4-sec butyl-2-methyl benzene.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i) A single monochloride.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:

i)Three isomeric monochlorides.

Among the isomeric alkanes of molecular formula C₅H₁₂, identify the one that on photochemical chlorination yields:
Four isomeric monochlorides.