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TextBook Solutions for Uttarakhand Board Class 12 Chemistry Chemistry I Chapter 9 Coordination Compounds

Question 1

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Write the formula for the following coordination compound:
Tetraaminediaquacobalt(lll)chloride

Solution

Tetraaminediaquacobalt(III) chloride [Co(NH₃)₄(H₂O)₂]Cl₃.

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TextBook Solutions for Uttarakhand Board Class 12 Chemistry Chemistry I Chapter 9 Coordination Compounds

Write the formula for the following coordination compound:
Tetraaminediaquacobalt(lll)chloride

Write the formula for the following coordination compound:
Potassium tetracyanidonickelate(II)

Write the formula for the following coordination compound:
Tris(ethane -1, 2-diamine) chromium(III) chloride

Write the formula for the following coordination compound:
Amminebromidochloridonitrito-N-platinate (II)

Write the formula for the following coordination compound:
Dichloridobis(ethane-1, 2-diamine)platinum(lV) nitrate.

Write the formula for the following coordination compound:
Iron(III) hexacyanidoferrate(II)

Write the IUPAC names of the following coordination compounds:
(i) [Co(NH₃)₆]Cl₃(ii) [Co(NH₃)₅Cl]Cl₂
(iii) K₃[Fe(CN)₆]
(iv) K₃[Fe(C₂O₄)_3]
(v) K₂[PdCl4]
(vi) [Pt(NH₃)₂Cl(NH₂CH₃)]Cl.

Indicate the type of isomerism exhibited by the following complexes and draw structures for these isomers:
(i) K[Cr(H₂O)₂(C₂O₄)₂], (ii) [Co(en)₃Cl₃,
(iii) [Co(NH₃)₅(NO₂)]|NO₃]₂, (iv) [Pt(NH₃)(H₂O)Cl₂]

Give evidence that [Co(NH₃)₅Cl]SO₄ and [Co(NH₃)₅SO₄]Cl are ionisation isomers.

Explain on the basis of valence bond theory that [Ni(CN)₄]^2– ion with square planar is diamagnetic and the [NiCl₄]^2– ion with tetrahedral geometry is paramagnetic.

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

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TextBook Solutions for Uttarakhand Board Class 12 Chemistry Chemistry I Chapter 9 Coordination Compounds

Write the formula for the following coordination compound:Tetraaminediaquacobalt(lll)chloride

Write the formula for the following coordination compound:Potassium tetracyanidonickelate(II)

Write the formula for the following coordination compound:Tris(ethane -1, 2-diamine) chromium(III) chloride

Write the formula for the following coordination compound:Amminebromidochloridonitrito-N-platinate (II)

Write the formula for the following coordination compound:Dichloridobis(ethane-1, 2-diamine)platinum(lV) nitrate.

Write the formula for the following coordination compound:Iron(III) hexacyanidoferrate(II)

Write the IUPAC names of the following coordination compounds:(i) [Co(NH3)6]Cl3(ii) [Co(NH3)5Cl]Cl2(iii) K3[Fe(CN)6](iv) K3[Fe(C2O4)3](v) K2[PdCl4] (vi) [Pt(NH3)2Cl(NH2CH3)]Cl.

Indicate the type of isomerism exhibited by the following complexes and draw structures for these isomers:(i) K[Cr(H2O)2(C2O4)2], (ii) [Co(en)3Cl3, (iii) [Co(NH3)5(NO2)]|NO3]2, (iv) [Pt(NH3)(H2O)Cl2]

Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionisation isomers.

Explain on the basis of valence bond theory that [Ni(CN)4]2– ion with square planar is diamagnetic and the [NiCl4]2– ion with tetrahedral geometry is paramagnetic.

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

Write the formula for the following coordination compound:
Tetraaminediaquacobalt(lll)chloride

Write the formula for the following coordination compound:
Potassium tetracyanidonickelate(II)

Write the formula for the following coordination compound:
Tris(ethane -1, 2-diamine) chromium(III) chloride

Write the formula for the following coordination compound:
Amminebromidochloridonitrito-N-platinate (II)

Write the formula for the following coordination compound:
Dichloridobis(ethane-1, 2-diamine)platinum(lV) nitrate.

Write the formula for the following coordination compound:
Iron(III) hexacyanidoferrate(II)

Write the IUPAC names of the following coordination compounds:
(i) [Co(NH₃)₆]Cl₃(ii) [Co(NH₃)₅Cl]Cl₂
(iii) K₃[Fe(CN)₆]
(iv) K₃[Fe(C₂O₄)_3]
(v) K₂[PdCl4]
(vi) [Pt(NH₃)₂Cl(NH₂CH₃)]Cl.

Indicate the type of isomerism exhibited by the following complexes and draw structures for these isomers:
(i) K[Cr(H₂O)₂(C₂O₄)₂], (ii) [Co(en)₃Cl₃,
(iii) [Co(NH₃)₅(NO₂)]|NO₃]₂, (iv) [Pt(NH₃)(H₂O)Cl₂]

Give evidence that [Co(NH₃)₅Cl]SO₄ and [Co(NH₃)₅SO₄]Cl are ionisation isomers.

Explain on the basis of valence bond theory that [Ni(CN)₄]^2– ion with square planar is diamagnetic and the [NiCl₄]^2– ion with tetrahedral geometry is paramagnetic.