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Amines
The correct statement regarding the basicity of arylamines is
Arylamines are generally more basic than alkylamines because the nitrogen lone pair electrons are not delocalized by interaction with the aromatic ring pi-electron system
Arylamines are generally more basic than alkylamines, because of aryl group
Arylamines are generally more basic than alkylamines because the nitrogen atom in arylamines is sp-hydridized.
Arylamines are generally less basic than alkylamines because the nitrogen lone pair electrons are delocalized by interaction with aromatic ring pi-electron system.
D.
Arylamines are generally less basic than alkylamines because the nitrogen lone pair electrons are delocalized by interaction with aromatic ring pi-electron system.
In the aryl amines, due to the delocalization of lone pair of electrons of N-atom to the benzene ring, it loses its basicity and becomes less basic than alkyl amine.
on the other hand, alkyl amines have +I alkyl effect of the alkyl group which increase electron density on N -atom. Hence the availability of free electron on amine as well as +I effects enhances its basic nature.
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