The d-And-f-Block Elements
Match the catalysis to the correct processes.
Catalyst | Process |
(A)TiCl3 | (i) Wacker Process |
(B) PdCl2 | (ii) Ziegler -Natta |
(C) CuCl2 | (iii) Contact process |
(D) V2O5 | (iv)Deacon's process |
(A)- (iii), (B)-(ii), (C)-iv, (D)- (i)
(A) - (ii), (B) - (i), (C) -(iv), (D) - (iii)
(A)- (ii), (B)- (iii), (C)- (iv), (D) - (i)
(A) - (iii) , (B) - (i), (C) - (ii), (D)- (iv)
B.
(A) - (ii), (B) - (i), (C) -(iv), (D) - (iii)
(i) TiCl3 is used as Ziegler- Natta catalyst for the polymerisation of ethene.
(ii) PdCl2 is used in Wacker process, in which alkene changed into aldehyde via catalytic cyclic process initiated by PdCl2.
(iii) CuCl2 is used in Deacon's process (for Cl2)
(iv) V2O5 is used in contact process manufacturing sulphuric acid.
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The outer electronic configuration of copper is 3d10 4s1, yet it is considered transition element. Why?
Name the first element of 3rd transition series.
Though copper, silver and gold have completely filled sets of d-orbitals yet they are considered as transition metals. Why?
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