General Principles And Processes of Isolation Of Elements
Name the chief forms of the occurrence of the following in the earth crust:
(a) aluminium, (b) calcium, (c) sodium, (d) lead.
(a) Aluminium: Oxides:
(i) CorundumAl2O3
(ii) DiasporeAl2O3.H2O
(iii) Bauxite Al2O3.2H2O
Halides: Cryolite Na3AlF6
Silicates:
(i) Feldspar KAlS3O8
(ii) Mica KAlSi3O10 (OH)2
(b) Calcium:Carbonate: Lime stone (CaCO3) marble, chalk, calcite and dolomite Sulphate : Gypsum, CaSO4 2H2O and anhydrite, CaSO4 Fluoride: Fluorspar, CaF2, Fluorapatite 3Ca3(PO4)2CaF2 Phosphate : Phosphorite, Ca3(PO4)2
(c) Sodium: Sodium chloride, NaCl
Sodium nitrate or chile salt petre NaNO3
Sodium carbonate Na2CO3 Borax Na2B4O7,10H2O.
(d) Lead: Anglesite, PbSO4 Cerussite PbCO3 Lanarkite, PbO, PbSO4.
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Titanium is a metal of modern times. It is obtained as oxide. Why it could not be extracted earlier despite its wide occurence?
Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present?
What criterion is followed for the selection of the stationary phase in chromatography?
What is the role of cryolite in the metallurgy of aluminium?
Why is zinc not extracted from zinc oxide through reduction using CO?
What is the role of graphite rod in the electrometallurgy of aluminium?
Predict conditions under which Al might be expected to reduce MgO.
Define the term gangue or matrix.
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