General Principles And Processes of Isolation Of Elements

Question

Carbon monoxide is more effective agent that carbon below 983 K but above this temperature the reverse is true. How would you explain this?

Answer

In the production of iron from its oxide ore, the mixture of ore, coke and limestone is heated with a blast of air in furnace. Below 983K oxides of iron are reduced by carbon monoxide to iron.

Fe2O3 +CO → 2FeO +CO2

FeO +CO → Fe + CO2

Above 983K, Fe2O3 undergoes reduction by hot coke to iron. This region is called fusion zone

Fe2O3 +3C → 2Fe  +3CO +Heat

Thus carbon monoxide is more effective agent than carbon below 983K.

 

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