Surface Chemistry

Question

How are the colloidal solutions classified on the basis of physical states of the dispersed phase and dispersion medium? 

Answer

Answer:
A dispersed phase or dispersion medium in colloidal solution may be a solid, liquid or gas. Based on physical states, 8 types of colloidal systems are possible (gas in gas is not possible as gases are always miscible in all proportions forming homogeneous mixure). All other takes of combinations of gases, liquids and solids may exist as colloidal solutions. Examples are given in the following table:

Internal phase of Dispersed phase

External phase or Dispersion medium

Colloidal name

Example

Solid

Solid

Solid sols

Alloys, Ruby glass, Gems or precious stones, marbles, optical and vision glasses.

 

Liquid

sols

Muddy water, gold sol, protein, starch, agar, gelatin in water, paints, pigments in water.

 

Gas

Aerosols (or solids

Smoke, particulate clouds.

Liquid

Solids

Gels

Cheese, jems, jellies, plants, fruits, vegetables

 

Liquid

Emulsions

Butter, milk, cosmetic products, e.g., shampoo, creams, emulsified oils, polish and medicines.

 

Gas

Aerosols (or liquids)

Fog, clouds, mist.

Gas

Solid

Solid foams

Pumicestone, styrene foam, foamed rubber, porous pot. thermocole rubber pillows and mattresses.

 

Liquid

Foams and froths

Lather, soap seeds, air bubble.

 

Gas

Homogeneous system

Do not exist as colloids.

 

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