The d-And-f-Block Elements
Assign reasons for the following:
Transition metals and their many compounds act as good catalyst.
Transition metals acts as catalyst due to the following reasons:
(i) Their partially empty d-orbitals provide surface area for reactant molecules.
(ii) They combine with reactant molecules to form transition states and lowers their activation energy.
(iii) They show multiple oxidation states and by giving electrons to reactants they form complexes and lower their energies.0
V2O5 (in contact process for manufacture of H2SO4), finely divided iron (in Haeber’s process for NH3 manufacture) and Ni (in catalytic hydrogenation) are examples of their good catalytic activities.
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How would you account for the irregular variation of ionisation enthalpies (first and second) in the first series of the transition elements?
The outer electronic configuration of copper is 3d10 4s1, yet it is considered transition element. Why?
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