The d-And-f-Block Elements

Question

Give example and suggest reasons for the following features of the transition metal chemistry:
The highest oxidation state is exhibited in oxoanions of a metal.

Answer

The highest oxidation state of transition element is seen in oxides and these oxides are acidic in nature. These acidic oxides dissolve in base and form oxoanions of transition metal. Thus oxoanions of transition element show highest oxidation state of transition metal. Examples are:
The highest oxidation state of Cr is +6 and it is observed that in its oxo-anion, CrO42–(chromate ion) and Cr2O72– (dichromate ion).

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