The d-And-f-Block Elements
In the case of p-block elements the valence electron are in np orbital. In this case, the valence electrons get unpaired and then excited to vacant d-orbital of the same energy level. Thereby exhibit variable oxidation state, e.g., in halogens.
But in the case of d-block elements these and (n – 1) d-electrons are lost. For example, Sc has the configuration [Ar]3d1s2. Therefore, it 4s electrons are lost it shows +2 and if in addition to 4s, 3d electrons are also lost than +3. Therefore, in the case of p-block elements the two oxidation states differ by two units, whereas in the case of d-block elements it differs by one unit only.
Sponsor Area
How would you account for the irregular variation of ionisation enthalpies (first and second) in the first series of the transition elements?
Sponsor Area
Sponsor Area