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The d-And-f-Block Elements
Explain the following facts:
Transition metals acts as catalyst.
Transition metals acts as catalyst due to the following reasons:
(i) Their partially empty d-orbitals provide surface area for reactant molecules.
(ii) They combine with reactant molecules to form transition states and lowers their activation energy.
(iii) They show multiple oxidation states and by giving electrons to reactants they form complexes and lower their energies.
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How would you account for the irregular variation of ionisation enthalpies (first and second) in the first series of the transition elements?
The outer electronic configuration of copper is 3d10 4s1, yet it is considered transition element. Why?
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