Classification of Elements and Periodicity in Properties

Question

Among the following which one has the highest cation to anion size ratio?

  • CsI

  • CsF

  • LiF

  • NaF

Answer

B.

CsF

The order of size of given cations is 
Li+ < Na+ < Cs+
and the order of the size of given anions is 


I- > F-
Thus, when the cation is largest and anion is smallest the cation to anion size ratio is maximum. Hence cation to anion size ratio is maximum

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