Thermodynamics
For a particular reversible reaction at temperature T, ΔH and ΔS were found to be both +ve. If Te is the temperature at equilibrium, the reaction would be spontaneous when
Te>T
T >Te
Te is 5 times T
T=Te
A.
Te>T
For a particular reversible reaction at T temperature
ΔG = ΔH-TΔS
When ΔH, S is positive
ΔG = +ΔH- T (+ΔS)
For a spontaneous process, ΔG must be negative, it is possible only at high temperature.
That mean T> Te
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