Redox Reactions

Question

What sorts of information can you draw from the following reaction?
(CN)2(g) + 2OH(aq) → CN(aq) + CNO(aq) + H2O(l)

Answer

The oxidation number of carbon in (CN)2, CN- and CNO- are +3, +2 and +4 respectively. These are obtained as shown below:

(CN)2: Let the oxidation number of C =x

2(x-3) =0

X= 3

CN-

x-3= -1

x=2

CNO-

X-3-2 =-1

X= 4

(i) The reaction involves the decomposition of cyanogen (CN)2 in alkaline medium.
(ii) Both (CN)2 (i.e. cyanogen) and CN- (i.e., cyanide ions) are pseudo halogens in nature i.e. both behave like halogens in characteristics.
(iii) Cyanogen undergoes disproportionation in the reaction.
(iv) It is an example of a redox reaction.

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