Redox Reactions

Question

Define the term oxidation, reduction, oxidation agent and reducing agent on the basis of oxidation number.

Answer

Oxidation: Oxidation is defined as a chemical reaction in which oxidation number of an element increases.
Reduction: Reduction is defined as a chemical reaction in which oxidation number of an element decreases.
Oxidising agent: Oxidising agent is a species which undergoes a decrease in oxidation number.
Reducing agent: Reducing agent is a species which undergoes an increase in oxidation number.
For example in the reaction:


The oxidation number of S increases from -2 to 0 while the oxidation number of Fe decreases from +3 (in FeCl3) to +2 (in FeCl2). Therefore H2S is oxidised and FeCl3 is reduced. Thus FeCl3 acts as an oxidising agent and H2S acts as a reducing agent.

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