Thermodynamics

Question

Why the heat of neutralisation is less than 57.1 kJ if either the acid or the base or both are weak?

Answer

If acid or base is weak its ionisation is not complete in aqueous solutions. Therefore,a part of the energy liberated during the combination of H+ ions and OH- ions is utilised for the ionisation of weak acid or base. Hence, the heat of neutralisation is less than 57.1KJ.

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