Classification of Elements and Periodicity in Properties

Question

How would you react to the statement that the electronegativity of N on Pauling scale is 3.0 in all the nitrogen compounds? 

Answer

The above statement is wrong because electronegativity of any given atom is not constant but varies with the state of hybridization and the oxidation state of the element. The electronegativity increases as the percentage of s-character of a hybrid orbital increases or oxidation state of the element increases. For example, the electronegativity of N increases as we move from sp3-sp2-sp hybrid orbitals. Similarly,electronegativity of N is different in NO3 and NH3.

Sponsor Area