Classification of Elements and Periodicity in Properties

Question

For each of the following pairs, state which one is larger in size and why?
(i) Na, Na+     (ii) Br, Br-    (iii) Br, I

Answer

(i) Na, Na+ pair. The size of Na atom is greater because the cation i.e. Na+ is formed by the loss of one electron from the atom.
(ii) Br, Br- pair. The size of Br- ion is greater as anion is formed by the gain of one electron by bromine atom.
(iii) Br, I pair. The size of 1 is greater because it comes after Br in the halogen family and atomic size increases down the group.

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