Hydrocarbons
What is ozonolysis? What is its significance?
Ozonolysis: When an alkene reacts with ozone in an inert solvent (ether, CCl4etc.), an explosive and unstable ozonide is formed. The ozonide undergoes hydrolysis producing carbonyl compounds. These two processes, the addition of O3 and hydrolysis are collectively called ozonolysis.
Significance: Ozonolysis is quite useful to locate the position of the double bond in an unknown alkene. This is done as shown below:
(i) Write the structures of the products (aldehydes or ketones or both) with carbonyl groups facing each other.
(ii) Remove oxygen atoms from carbonyl carbon and connect them by a double bond. For example, suppose the products of ozonolysis are ethanal and propanone.
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Define cracking.
What is the function of iodic acid in the iodination of alkanes? Can we use any other substance in its place?
What is alternation effect?
Arrange the following compounds in order of their increasing boiling points:
n-Pentane, n-Hexane, Ethane, 2-2-Dimethylpentane, 2-Methylpentane.
Why is light or heat necessary to initiate chlorination reaction of alkanes?
What are conformation or rotational isomers?
Can you separate the two conformations of ethane?
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