Hydrocarbons
Alkanes contain only carbon-carbon and carbon - hydrogen single bonds. For example methane.
Therefore, carbon in alkanes is sp3 - hybridised. Since sp3 hybridised carbon has four half filled sp3 - orbitals, therefore, it forms four σ-bonds. These four bonds are directed towards the corners of a regular tetrahedron. In other words, the angle between any two adjacent bonds is 109° - 28' (tetrahedral angle).
In methane molecule, carbon lies at the centre of the tetrahedron while the four hydrogens are present at the corners of vertices of the regular tetrahedron. This implies that; each face of the tetrahedron is an equilateral triangle and has three bonds.
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During the pyrolysis of alkanes C-C bonds break in preference to C-H bond. Why?
Define cracking.
What is the function of iodic acid in the iodination of alkanes? Can we use any other substance in its place?
What is alternation effect?
Arrange the following compounds in order of their increasing boiling points:
n-Pentane, n-Hexane, Ethane, 2-2-Dimethylpentane, 2-Methylpentane.
Why is light or heat necessary to initiate chlorination reaction of alkanes?
What are conformation or rotational isomers?
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