Organic Chemistry – Some Basic Principles and Techniques

Question

Write a short note on Beilstein test.

Answer

Beilstein test: This test is employed to detect the presence of halogen in an organic compound. A clean copper wire flattened at one end is heated in the oxidising flame till it imparts no colour to the flame. The appearance of blue or green colour due to the formation of volatile copper halide indicates the presence of halogens in the organic compound.
Limitations. This test is not very reliable because:
(i) Compounds like pyridine, urea and thiourea, which do not contain halogens, also respond to this test.
(ii) It does not tell which member of the halogen family is present in the organic compound.

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