Organic Chemistry – Some Basic Principles and Techniques
The atomic number of carbon is 6 and its electronic configuration is 2, 4. In other words, carbon has four electrons in the valence shell and thus needs four more electrons to complete its octet. Therefore carbon is tetravalent. Since carbon atom has high ionisation energy and moderate electron affinity, therefore it is very difficult for carbon to either lose or gain four electrons to achieve the nearest inert gas configuration. Consequently, carbon always combines with other atoms by mutual sharing of electrons and thus forms covalent bonds. Thus, carbon is always tetravalent i.e. it forms four covalent bonds with other atoms.
According to Le Bel and van’t Hoff, the four bonds of a carbon atom are directed towards the four corners of a regular tetrahedron. The carbon atom lies at the centre of a regular tetrahedron and the angle between any two adjacent bonds is 109° – 28' or 109.5°. This arrangement of carbon atom is regarded as a tetrahedral model or carbon or space model.
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Which characteristic is common to different isomers of a compound?
Name three alkanes which do not show chain isomerism.
Name the types of structural isomerism shown by alkanes.
Name the four main types of structural isomerism.
Write the three possible open chains of five carbon atoms
What types of structural isomerism is shown by the following pairs of organic compounds ?
Draw the structure of the tautomer of phenol and write its IUPAC name.
Define ring - chain isomerism. Given one example.?
Write the metamer of diethyl ether ?
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